| MATERIAL
SAFETY DATA SHEET (MSDS) |
"TOYOLAC"
General Purpose ABS Resin
Grade Name : "TOYOLAC" 100, 250, 300,
325, 500, 700
MSDS No. : TPM001 Toray Plastics (Malaysia) Sdn. Bhd.
Date : 1 November, 2000 |
| 1. COMPANY / IDENTIFICATION |
1.1
NAME OF MANUFACTURER / SUPPLIER
ADDRESS : 2628 MK.1,SPT., Lorong Perusahann 4, Prai
Free Industrial Zone, 13600 Prai, Penang, Malaysia.
1.2 SAFETY MANAGER
| PRODUCTION, TECHNOLOGY |
|
| DIVISION |
: Production Division |
| MANAGER |
: Director & Factory Manager |
| SALES |
|
| DIVISION |
: Sales & Marketing Division |
| MANAGER |
: General Manager |
1.3 MSDS MANAGER
| DEPT. |
: Technical Department |
| MANAGER |
: Technical Department Manager |
1.4 INFORMATION CENTER (CUSTOMER SERVICE CENTER)
| DEPT. |
: Sales & Marketing Department |
| ADDRESS |
: 2628 MK.1, SPT.,Lorong Perusahann 4, Prai Free
Industrial Zone, 13600 Prai, Penang, Malaysia. |
| Tel. No. |
: +60 4 3988088 |
| Fax. No. |
: +60 4 3908975, 39977264 |
|
| 2. COMPOSITION
/ INFORMATION ON INGREDIENTS |
| CHEMICAL NAME |
: Acrylonitrile-Butadiene-Styrene Copolymer |
| NAME |
: ABS Resin |
| ABBREVIATION NAME |
: - |
| CAS NUMBER |
: 9003-56-9 |
| SUBSTANCE (O) MIXTURE ( ) ; UN CLASS
&UN NUMBER |
| CHEMICAL NAME |
COMP(%) |
CHEMICAL FORMULA(CONSTITUTIONAL FORMULA,STRUCTURAL FORMULA) |
CAS No. |
TSCAStatus |
| Acrylonitrile-Butadiene-Styrene Copolymer |
100 |
-[(C8H8)k-(C3H3N)l-(C4H6)m]n- |
9003-56-9 |
Inventoried |
|
| 3. HAZARDS
IDENTIFICATION |
3.1
EMERGENCY OVERVIEW
Opaque yellowish white or colored pellets with slight
or no odor. Slipped pellets create slipping hazard. It can burn
in a fire with toxic smoke. Melted material can cause serious burns.
Fumes and smoke generated during melt processing may cause eye,
skin and respiratory tract irritation. Secondary processing can
produce dust, which may cause respiratory hazard and an explosion.
3.2 CLASS NAME OF HAZARDS CHEMICALS FOR
MSDS IN JAPAN
Not Applicable.
3.3 PHYSICAL & CHEMICAL HAZARDS
Not Applicable.
3.4 POTENTIAL HUMAN HEALTH EFFECTS
Eye :
May cause irritation or injury due to mechanical action.
Skin : Pellets not
likely to cause skin irritation.
Ingestion : Not acute toxicity.
Inhalation : Pellet inhalation unlikely due to its physical
form.
3.5 ENVIRONMENTAL EFFECTS
Not Applicable.
3.6 OTHERS
See REGULATORY INFORMATION. |
| 4. FIRST-AID
MEASURES |
4.1 INHALATION
Not likely to be inhaled due to its physical form. However, if symptoms
are experienced, move victim to fresh air place. Seek medical assistance
for further treatment, observation and support if necessary.
For processing fume inhalation irritation, leave contaminated area
and breathe fresh air. If coughing, difficult breathing or any other
symptoms develop seek medical assistance at once, even if symptoms
develop at a later time.
4.2 SKIN CONTACT
Wash skin thoroughly with soap and gently water. Seek medical assistance
for further treatment, observation and support if necessary.
For molten resin skin contact, cool rapidly with water and immediately
seek medical assistance. Do not attempt removal of resin without
medical assistance. Do not use solvent for removal.
For skin contact with fume condensate, immediately wash thoroughly
with soap and water. If irritation develops seek medical assistance.
4.3 EYE CONTACT
Remove contact lenses at once. Immediately flush the
contaminated eye(s) with gently clear water or normal saline for
at least 20-30 minutes. Seek medical assistance for further treatment,
observation and support if necessary.
4.4 INGESTION
Have victim rinse mouth thoroughly with water. Seek
medical assistance for further treatment, observation and support
if necessary. |
| 5. FIRE FIGHTING MEASURES |
5.1
SPECIFIC HAZARDS WITH REGARD TO FIRE FIGHTING MEASURES
Apply water from a safe distance to cool and protect area. Move
container from fire area if it can be done without risk. Keep personnel
to safe area. The heat generated by a fire will liberate toxic fumes
and smoke, such as dense black smoke, carbon monoxide, carbon dioxide,
hydrogen cyanide and hydrocarbon fragments. Breathing apparatus
that is approved pressure demand and protective clothing should
be used for all fires.
5.2 EXTINGUISHING
MEDIA
Water spray, carbon dioxide foam, polymer foam and dry chemical
foam. Water spray is the best extinguishing medium. Carbon dioxide
and dry chemical foam are not generally recommended because their
lack of cooling capacity may permit re-ignition.
|
| 6. ACCIDENTAL RELEASE MEASURES
|
6.1
MEASURES FOR HANDLING PERSONNEL
Shut off all sources of ignition and wear dust mask if dust is
presents.
6.2 MEASURES
FOR ENVIRONMENTAL EFFECTS
Do not flush to sewer or drain. In case of huge amount is released
and spilled, it may cause environmental impact
of pollution.
6.3 MEASURES
WHEN HANDLING SPILLED SUBSTANCES
Restrict access to area until completion of clean up. Shovel into
clean, labeled containers and cover. Sweep or gather up material
immediately and place in proper container for disposal and recovery.
|
| 7. HANDLING
AND STORAGE |
7.1
HANDLING
Exposure control for handling personnel:
Ventilate the room in order to remove dust, heat and products of
pyrolysis.
Use good industrial hygiene practices.
Prevent contact with skin and eyes.
Protective measures against fire & explosion:
Prevent accumulation of dust.
Avoid generating fumes or dust.
Take precautionary measures against static discharges.
In case of fire and/or explosion, do not breathe fumes.
Others:
Avoid rough handling or dropping.
Do not flush to sewer or drain.
7.2
STORAGE
Store in a dry place away from moisture, excessive heat, sunlight
and sources of ignition.
|
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION |
8.1
CONTROL PARAMETER
|
|
CONTENT
(%) |
Acrylonitrile -Butadiene
-Styrene Copolymer |
|
| Labor Safety & Health Act (Japan) |
ppm(mg/m³) |
Total dust :
8(mg/m³) |
|
| ACGIH |
ppm(mg/m³) |
Total dust :
10(mg/m³) |
|
| OSHA |
ppm(mg/m³) |
|
|
Neither Japan Association of Industrial Health and Hygiene
nor ACGIH specifies the tolerable concentration of ABS resin dust,
but it is believed that the above values are reasonable guidelines
for operation.
8.2 ENGINEERING
MEASURES
In order to keep suitable working environment, a continuous supply
of fresh air with ventilation systems is recommended.
Local Exhaust :
Required when material is heated at more than 200°C.
Special :
Use process enclosure if necessary to control airborne smelling.
If engineering controls are not effective in controlling exposure
to this material or its fumes or impurities, then wear suitable
personal protective equipment including approved respiratory protection
as mentioned below.
8.3 PERSONAL PROTECTION
Eye / Face :
Wear safety glasses with side shields or chemical goggles. Moreover,
useful face shield when processing fumes condenses from hoods, ducts
and other surfaces.
Skin :
Wear safety gloves to prevent any contact with processing fume condenses.
Wear long pants, long sleeves and safety shoes when applicable.
Respiratory :
When processing fumes, and dust or powder form secondary processing
are not adequately controlled, use respiratory approved for protection
from organic vapors and gases. |
| 9. PHYSICAL & CHEMICAL PROPERTIES |
| Physical State |
: |
Solid |
Vapor pressure |
: |
Negligible |
| Appearance |
: |
Plastic pellet |
Vapor density |
: |
Not Applicable (air = 1) |
| Odor
|
: |
Slight odor |
Specific gravity |
: |
1.01-1.06 (water = 1) |
| Boiling point |
: |
Not Applicable |
Solubility(%) |
in water : |
Insoluble |
| Melting point |
: |
See COMMENT below |
|
in others : |
Soluble in organic solvents |
| Volatility |
: |
Negligible |
pH |
: |
Not Applicable |
| Odor Threshold |
: |
Not Established |
Evaporation rate |
: |
Negligible |
COMMENT : This product does not exhibit a sharp melting point, but it softens
gradually over a broad temperature range, between 100-150°C. |
| 10. STABILITY
& REACTIVITY |
| Flash point : |
Not Applicable |
Autoignition temperature : |
405°C, estimated |
| Explosion limit(%) : |
|
Combustibility : |
|
| Upper : |
Not established |
Spontaneous : |
Not Applicable |
| Lower : |
60g/m3(Particle size<200nm) |
Reactivity with water : |
Not Applicable |
| Flammable limit(%) |
|
Flammability : |
Inflammable |
| Upper : |
Not established |
(Requires a continuous flame source to ignite) |
| Lower : |
Not established |
| Flammability : |
Inflammable |
Dust explosion : |
See Explosion limit |
| Oxidizibility : |
Not Applicable |
Self-reactivity : |
Not Applicable |
STABILITY & REACTIVITY
This product is considered a stable material under recommended
conditions of storage and handling. And it is not reactive material
under recommended conditions of handling, storage, processing and
use.
CONDITIONS TO AVOID:
Do not exceed recommended melt temperature. In order to prevent
autoignition and hazardous decomposition of hot lump of purged material,
it should be collected in small, flat shapes or thin strands to
allow for rapid cooling and quench in water. Do not allow product
to remain in barrel at elevated temperatures for extended periods
of time.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
Processing fumes evolved at recommended processing conditions may
include trace level of Styrene, Acrylonitrile, Acrolein, Acetaldehyde,
Acetophenone, Ethylbenzene, Cumene, 4-vinylcyclohexene and phenols.
When it is burned, hazardous combustion products may include intense
heat, dense black smoke, carbon monoxide, carbon dioxide, hydrogen
cyanide and hydrocarbon fragments. |
| 11. TOXICOLOGICAL
INFORMATION |
| Acute toxicity |
: |
Oral LD50 (Rat) >5 g/kg
(estimated) |
| Sub-acute toxicity |
: |
No specific information is available. |
| Chronic toxicity |
: |
No specific information is available. |
| Carcinogenic effects
|
: |
No specific information is available. |
| Mutagenic effects |
: |
No specific information is available. |
| Irritant properties |
: |
Processing fumes will irritate skin and eyes. |
| Allergenic and Sensitizing effects |
: |
The formed gas and fume have sensitivity. |
| Teratogenic effects |
: |
No specific information is available. |
| Others |
: |
Styrene monomer is listed as a possible carcinogen by
IARC. Rats exposed to acrylonitrile by repeatedly orally and
inhalation induced brain and stomach tumors. |
|
| 12. ECOLOGICAL
INFORMATION |
| Biodegradability |
|
No specific information is available. |
| Bioaccumulation |
|
No specific information is available. |
| Fish toxicity |
|
No specific information is available. |
|
| 13. DISPOSAL CONSIDERATION |
| Do not dump this product
into sewers, any ocean or water area in order to prevent marine animals
and birds from ingesting. Recycling is encouraged. Disposal by controlled
incineration or source landfill in accordance with governing body
requirements may be acceptable. |
| 14. TRANSPORT INFORMATION |
Avoid
wetting and rough handling in order to maintain suitable packing
condition. In case the packing is damaged and released pellets or
powder, sweep or gather up material and place in proper container
for disposal or recovery.
(See ACCIDENTAL RELEASE MEASURES and DISPOSAL INFORMATION). |
| 15. REGULATORY INFORMATION |
|
REGULATORY / CLASSIFICATION |
Regulatory Information |
Allowed Concentration |
| TSCA(USA) |
This product complies with the Chemical Substance Inventory requirements
of the US EPA Toxic Substances Control Act. |
|
| EINECS No. |
- |
|
| California Proposition 65 |
Chemical substances identified under the California Proposition 65 column
are known to the State of California to cause cancer and/or
reproductive toxicity. |
|
| FDA |
- |
|
| UL |
Registered |
|
| CSA |
Registered |
|
| OSHA |
Not Regulated |
|
Other regulatory information
We are not able to check up the regulatory information in regard
to the substances in your country or region. Therefore, we request
this matter would be filled by your responsibility. Regulatory information
with regard to this substance in your country or in your region
should be examined by your own responsibility. Ensure this matter
in compliance with federal requirements and ensure conformity to
local regulations. |
| 16. OTHER INFORMATION / REFERENCES |
| This information relates
to this specific material. It may not be valid for this material,
if used in combination with any other materials or in any process.
It is user responsibility to satisfy him-selves as to the suitability
and completeness of this information for his own particular use. The
information herein is given in good faith, but no warranty, express
or implied, is made. Please consult us for further information. To
the best of our knowledge, the information contained herein is accurate.
However, we assume any liability whatsoever for the accuracy or completeness
of the information contained herein. Final determination of suitability
of any material is the sole responsibility of user. All materials
may present unknown hazards and should be used in caution. Although
certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist. This information contained in this
data sheet represents the best information currently available to
us. However, no warranty is made with respect to its completeness
and we assume no liability resulting from its use. It is advised to
make their own tests to determine the safety and suitability of each
such product or combination for their own purposes. |
| Go
back |